Sure - auto ignition is >800*F at atmospheric... but those aren't intra-cylinder conditions.
Several environmental factors can change a chemical's AIT - a CI engine has at least 4 that serve to reduce methanol's.
Hey Mike!!!
Can you expound on this? I always enjoy your posts, and am not doubting what you say here; rather, I'm just trying to make sense of everything.
Here's a quick background on what's got me thinking:
There has been recent work in light duty diesel engines running in an RCCI combustion mode (reactivity controlled compression ignition), where gasoline is injected in the intake manifold via PFI injectors, and the diesel is injected normally via DI injectors on the engine. At moderate loads, significant amounts of gasoline are injected (~60 - 80% of total fueling) into the intake plenum, and then the DI diesel event phased accordingly for proper combustion.
Surprisingly (to me at least), the introduction of semi-premixed gasoline serves to
retard injection timing, very similar to how heavy EGR delays ignition. For example, when running 60% gasoline, injection timing of the DI diesel event is ~37° btdc. When running 80% gasoline, DI timing is ~ 60° btdc.
When combustion occurs in this RCCI mode, it happens very quickly...i.e., there is no "tail" on heat release as things continue to burn. It lights off and burns rapidly. The efficiency benefit comes from being able to center combustion phasing (CA50 point, or 50% mass fraction burned) immediately after TDC, and having all effective work due to combustion done within 20 - 30° atdc!
Gasoline generally is thought to have an AIT of ~ 250 - 260° C, whereas methanol's AIT is much higher, at around 450 - 470° C. I know that people say running methanol injection on our trucks advances timing, but I haven't reconciled this with the data from the RCCI combustion that I know is true.
Additionally, "In general, aromatics and alcohols have low cetane numbers (that's why people using methanol in diesels convert it to dimethyl ether). One of the obvious effects of running on low cetane number fuel is the increase in engine noise." Low cetane tends toward longer ignition delay, and agrees with the RCCI data. But methanol?
Interested in hearing your thoughts...
--Eric