Smokem said:
Your are contradicting yourself here. Cetane has nothing to do with pressure.
Ah contraire my good man. The higher the cetane number, the more easily the fuel can be ignited. What causes auto ignition? Pressure right? Hence the lack of spark plugs to induce ignition. I understand there is a defined baseline testing process to derive the value but I contend that measure is directly based on the ability of the fuel to auto ignited under pressure. There also may be a burn speed component as well. Good stuff though. Thanks.
What are you mumbling about Commie hater lol?
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The performance rating of a diesel fuel, corresponding to the percentage of cetane in a cetane-methylnaphthalene mixture with the same ignition performance. A higher cetane number indicates greater fuel efficiency. Also called cetane rating.
A number, usually between 30 and 60, that indicates the ability of a diesel engine fuel to ignite quickly after being injected into the cylinder. The higher the cetane number, the more easily the fuel can be ignited. In high-speed diesel engines, a fuel with a long ignition delay tends to produce rough operation. See also Diesel engine; Diesel fuel.
Cetane number or CN a measure of the combustion quality of distillate diesel fuel under compression. It is often mistaken as a measure of fuel quality. Cetane number is actually a measure of a fuel's ignition delay. This is the time period between the start of injection and start of combustion (ignition) of the fuel. In a particular diesel engine, higher cetane fuels will have shorter ignition delay periods than lower cetane fuels. Cetane numbers are only used for the relatively light diesel oils. For heavy fuel oil two other scales are used CCAI and CII.
Characteristics
A fuel with a high cetane number starts to burn shortly after it is injected into the cylinder; it has a short ignition delay period. Conversely, a fuel with a low cetane number resists auto-ignition and has a longer ignition delay period.
Diesel engines run well with a CN between 45 to 50. There is no performance or emission advantage when the CN is raised past 50; after this point, the fuel's performance hits a plateau.
Diesel at the pump can be found in two CN ranges: 40-46 for regular diesel, and 45-50 for premium. Premium diesel has additives to improve CN and lubricity, detergents to clean the fuel injectors and minimize carbon deposits, water dispersants, and other additives depending on geographical and seasonal needs.
Alkyl nitrates and di-tert-butyl peroxide are used as additives to raise the cetane number.
Comparison to Octane Rating
Cetane rating is sometimes thought of the diesel equivalent of gasoline's octane rating. One must also consider that the higher the octane number, the lower the cetane number. This is because gasoline's desirable property is to resist autoignition to prevent engine knocking whereas diesel's desirable property is to autoignite.[1]
A cetane limit is the minimum cetane number that a fuel must have to meet specifications. Octane ratings give an ideal range that will minimize engine knocking.
Chemical Relavance
Cetane is an alkane molecule that ignites very easily under compression, so it was assigned a cetane number of 100. All other hydrocarbons in diesel fuel are indexed to cetane as to how well they ignite under compression. The cetane number therefore measures how quickly the fuel starts to burn (auto-ignites) under diesel engine conditions. Since there are hundreds of components in diesel fuel, with each having a different cetane quality, the overall cetane number of the diesel is the average cetane quality of all the components. There is very little actual cetane in diesel fuel.
Measuring Cetane Number
To measure cetane number properly is rather difficult, as it requires burning the fuel in a special, hard-to-find, diesel engine called a Cooperative Fuel Research (CFR) engine, under standard test conditions. For most practical purposes, fuel-users control quality using the Cetane Index, which is a calculated number based on the density and distillation range of the fuel. There are various versions of this, depending on whether you use metric or Imperial units, and how many distillation point are used. These days most oil companies use the '4-point method'.
Further Reading
* Internal Combustion Engine Fundamentals, John B. Heywood, McGraw Hill, 1988 ISBN 0-07-100499-8
* Automotive Fuels Reference Book, Keith Owen, Trevor Coley SAE, 1995, ISBN 1-56091-589-7