In theory, you need to do the calculations based on pressure ratios; they should be balanced. Gauge pressure is also pressure above atmosphere, so you need to convert to absolute pressure. At sea level, it's about 14.7psi, which means you're seeing (14.7 +18)=32.7psia blowing into the small charger, which is making (40+14.7)=54.7psia.
So your pressure ratio for the big charger (32.7/14.7)=2.22:1
And high=pressure charger (32.7/54.7)=1.67:1
This actually isn't bad, normally compounds are pretty far off. For instance, my 57/71mm combo made 40psi out of the big charger, while the small turbo was barely doing anything. However, it also made 60psi of boost with 65psi of drive.
So here's my guess....on my 95, an HX35 made 42psi by itself at c.430rwhp, so I think your big charger is basically pushing enough air onto the HX35 to make its drive pressure higher, but not really enough to raise your total boost up. The atmosphere charger on my 95 is a 71/74/.85 a/r, so it's doing a whole lot more work than the big turbine wheel deal you have on there. If it were my truck, I would add some bigger injectors and more timing, and call it good.