You are having pre-ignition anytime the propane is in the engine.
Before TDC without boost the air temp is increased enough to burn diesel when it is injected into the cylinder (14*-20* BTDC). If not the engine would not idle.
The temps are high enough to ignite diesel in an 11:1 engine running 48* of timing. Not ignite very well but it is burning.
As stated before:
Propane auto-ignites at 842*F
Diesel auto-ignites at 410*F
Wait before you look too far into that.
The flash point of propane is 152*, and diesel is 143*.
Your average cylinder temp in a diesel engine is around 1000*F. Now if there is 900* in the cylinder at 48* BTDC with 11:1 compression, you know good and well a stock engine has more that enough to lite the propane way before TDC, likely not more than a 20* off BDC. Then at 10psi to that CR and see where your cylinder temps are.
Lets assume that your propane is only igniting at 60* BTDC at no boost. You engine is seeing the same stress as a engine running that timing at the same power level.